[μ-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- κ2 O,O′)cadmium(II)]
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چکیده
The complete title complex, [Cd(2)(NO(3))(4)(C(30)H(42)N(15)P(3))], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclo-triphosphazene ligand located on the rotation axis. The non-planar cyclo-triphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cyclo-triphosphazene N atom.
منابع مشابه
[μ3-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2λ5,4λ5,6λ5-1,3,5,2,4,6-triazatriphosphinine]tris[cis-dichloridopalladium(II)]
The title complex, [Pd(3)Cl(6)(C(30)H(42)N(15)P(3))], possesses C(3) mol-ecular symmetry. The P and N atoms of the cyclo-triphosphazene and the Pd atom are located on the crystallographic mirror plane. Each of the three symmetry-related Pd atoms is coordinated by two chloride ligands and two exocyclic pyrazolyl N atoms, but not by the cyclo-triphosphazene N atoms.
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